47653
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47653
Fluka
Bis(methylthio)methane
purum, ≥95.0% (GC)
| Synonym: | Dimethylthiomethane, Formaldehyde dimethyl mercaptal |
| CAS Number: | 1618-26-4 |
| Linear Formula: | CH3SCH2SCH3 |
| Molecular Weight: | 108.23 |
| Beilstein Registry Number: | 1731143 |
| EC Number: | 216-577-9 |
| MDL number: | MFCD00008564 |
| PubChem Substance ID: | 24871266 |
Description
| Other Notes | Acyl anion equivalent useful for many transformations1,2,3,4 |
Properties
| grade | purum |
| assay | ≥95.0% (GC) |
| refractive index | n |
| n | |
| bp | 147 °C(lit.) |
| density | 1.059 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 16-26-36/37/39 |
| RIDADR | UN1993 3/PG 3 |
| WGK Germany | 3 |
| Flash Point(F) | 111.2 °F |
| Flash Point(C) | 44 °C |
References
| Cited Reference | 1. M. Braun, D. Seebach Chem. Ber. 109, 669, (1976) |
| 2. M.L. Quesala, R.H. Schlessinger Synth. Commun. 6, 555, (1976) | |
| 3. B.M. Trost, E. Murayama Tetrahedron Lett. 23, 1047, (1982) | |
| 4. K. Narasaka et al. Chem. Lett. (Jpn), 1411, (1990) | |
| Merck | Merck 13,1255 |
| Beilstein | Beil. 1,IV,3088 |
| reference | Aldrich MSDS 1, 201:C / Corp MSDS 1 (1), 440:D / FT-IR 2 (1), 419:D / FT-IR 1 (1), 264:D / FT-NMR 1 (1), 426:A / NMR-Reference 2 (1), 215:C / RegBook 1 (1), 285:D / Structure Index 1, 39:B:1 / Vapor Phase 3, 347:D |
